Crystallographic Structure Determination of MFI-Zeolite Nanosheets
نویسندگان
چکیده
منابع مشابه
Crystallographic Structure Determination of MFI-Zeolite Nanosheets
Ultrathin MFI-zeolite nanosheets can be packed on porous supports to create molecular sieve membranes. The nanosheets on porous support reduce morphological damage seen in regular MFIzeolite crystals [1]. MFI-zeolite belongs to pentasil family of zeolites where the periodic building unit (PerBU) is composed of 12 interconnected SiO4 tetrahedral (T12) units of 41m2 (D2d) symmetry [2]. Rotation o...
متن کامل2D Zeolite Coatings: Langmuir-Schaefer Deposition of 3 nm Thick MFI Zeolite Nanosheets.
Stable suspensions of zeolite nanosheets (3 nm thick MFI layers) were prepared in ethanol following acid treatment, which partially removed the associated organic structure-directing agent. Nanosheets from these suspensions could then be dispersed at the air-water interface and transferred to silicon wafers using Langmuir-Schaefer deposition. Using layer-by-layer deposition, control on coating ...
متن کاملMFI zeolite nanosheets with post-synthetic Ti grafting for catalytic epoxidation of bulky olefins using H2O2.
The external surfaces of the surfactant-directed, 2.5 nm MFI zeolite nanosheets were grafted with Ti using titanium(IV) butoxide. The Ti/MFI nanosheets exhibited a remarkable catalytic performance for epoxidation of bulky olefins using H2O2 as an oxidant, in comparison to the mesoporous silicas with amorphous frameworks.
متن کاملSynthesis and characterization of MFI zeolite nanosheets for optimizing the dominant operational conditions of methanol to propylene process
Nanosheets of MFI zeolite were successfully synthesized by hydrothermal method and were properly characterized by XRD, FE-SEM, EDX-dot mapping, TEM, FT-IR, N2 adsorption/desorption, NH3-TPD, ICP-AES and TGA techniques. The characterizations of MFI zeolite nanosheets suitably confirmed well synthesized MFI nanostructure, superior specific surface area (695.96m2.g-1) and great mesopores volume. C...
متن کاملOpen-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports.
Two-dimensional zeolite nanosheets that do not contain any organic structure-directing agents were prepared from a multilamellar MFI (ML-MFI) zeolite. ML-MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H2 SO4 and H2 O2 (piranha solution). The obtained OSDA-free MFI nanosheets disperse well in water and can be used for coating applications. Deposi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Microscopy and Microanalysis
سال: 2014
ISSN: 1431-9276,1435-8115
DOI: 10.1017/s1431927614003675